Peppol validation error vs Access Point rejection
Short answer: a structurally valid XML document may still fail business rules, Peppol-specific rules, electronic-address routing or requirements applied by a country, platform or receiver.
The validation layers
Why the rejection message matters
The exact code identifies which layer failed. A parsing error requires different action from a BR-CO total mismatch or a missing EndpointID. Always work from the newest rejection report rather than assuming that every rejection has the same cause.
Why one successful check is not a guarantee
Tools may implement different rule sets or releases. An Access Point may also apply network, receiver or jurisdiction-specific controls beyond the checks performed locally.
What to do next
Locate the exact rule in the current Peppol documentation, compare the related XML value with the source business record, regenerate the invoice, validate again and resubmit through the normal Access Point workflow.